New microarchitectures of (Er,Yb):Lu2O3 nanocrystals embedded in PMMA: synthesis, structural characterization, and luminescent properties

نویسندگان

  • Montserrat Galceran
  • Maria Cinta Pujol
  • Joan Josep Carvajal
  • Xavier Mateos
  • Pilar Formentín
  • Josep Pallarès
  • Lluis Francesc Marsal
  • Kyung Ho Park
  • Fabian Rotermund
  • Kihong Kim
  • Magdalena Aguiló
  • Francesc Díaz
چکیده

We report the formation of two-dimensional disordered arrays of poly(methyl)methacrylate (PMMA) microcolumns with embedded single size distribution of Lu0.990Er0.520Yb0.490 nanocrystals, (Er,Yb):Lu2O3, using a disordered porous silicon template. The cubic (Er,Yb):Lu2O3 nanocrystals, which crystallize into the cubic system with Ia3¯ space group, were synthesized using the modified Pechini method. Electronic microscopic techniques were used to study the distribution of the nanocrystals in the PMMA columns. Cathodoluminescence was used to observe the visible luminescence of the particles. Red emission attributed to 4 F9/2 → 4I15/2 erbium transition is predominant in these new composites.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis of NaLuF4-based nanocrystals and large enhancement of upconversion luminescence of NaLuF4:Gd, Yb, Er by coating an active shell for bioimaging.

A series of NaLuF4-based hexagonal phase upconversion nanocrystals (UCNs) were synthesized by a facile solvothermal method and the properties of the UCNs were investigated. The results show that the as-prepared nanocrystals exhibit pure hexagonal lattice structures, uniform morphologies, high monodispersities and excellent upconversion luminescence. The upconversion luminescence (UCL) intensiti...

متن کامل

Bi-functional NaLuF4:Gd3+/Yb3+/Er3+ nanocrystals: hydrothermal synthesis, optical and magnetic properties

Magnetic-fluorescent lanthanide doped sodium lutetium fluoride (NaLuF4:Yb3+/Er3+/Gd3+) nanocrystals were synthesized via facile hydrothermal method by varying concentration of Gd3+. Powder X-ray powder diffraction (PXRD), scanning electron microscopy (SEM),transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), p...

متن کامل

Aqueous phase synthesis of upconversion nanocrystals through layer-by-layer epitaxial growth for in vivo X-ray computed tomography.

Lanthanide-doped core-shell upconversion nanocrystals (UCNCs) have tremendous potential for applications in many fields, especially in bio-imaging and medical therapy. As core-shell UCNCs are mostly synthesized in organic solvents, tedious organic-aqueous phase transfer processes are usually needed for their use in bio-applications. Herein, we demonstrate the first example of one-step synthesis...

متن کامل

Color control and white upconversion luminescence of LaOF:Ln3+ (Ln = Yb, Er, Tm) nanocrystals prepared by the sol-gel Pechini method.

A series of Yb(3+)-Er(3+) and Yb(3+)-Er(3+)-Tm(3+) codoped LaOF nanocrystals were synthesized via a modified sol-gel Pechini method. The phases and morphologies as well as the luminescence properties of the as-prepared samples were characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and upconversion luminescence (UCL) spectra, respectively. Under 980 nm near in...

متن کامل

Synthesis, Characterization, Luminescent Properties, And Crystal Structure Determination Of a New Platinium (IV) Complexe : trans-[Pt(4-mpy)2Cl4]

The new trans-[Pt(4-mpy)2Cl4] (1) complex (4-mpy is 4-methylpyridine) was prepared from the reaction of H2PtCl6.6H2O with 4-methylpyridine in methanol. Synthesized complex was thoroughly characterized by elemental analysis, IR and 1H-NMR spectroscopy.Elemental analysis data (C, H, N) support the general composition of the title complex and the structure have been established by single-crystal X...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 8  شماره 

صفحات  -

تاریخ انتشار 2013